- AutorIn
- Ines Maria Hauptvogel
- Volodymyr Bon
- Ronny Grünker
- Igor A. Baburin
- Irena Senkovska
- Uwe Müller
- Stefan Kaskel
- Titel
- A family of 2D and 3D coordination polymers involving a trigonal tritopic linker
- Zitierfähige Url:
- https://nbn-resolving.org/urn:nbn:de:bsz:14-qucosa-138965
- Quellenangabe
- Dalton Transactions 2012;41: 4172–4179, ISSN: 1477-9226
- Erstveröffentlichung
- 2012
- Abstract (DE)
- Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
- Abstract (EN)
- Five new coordination polymers, namely, [Zn2(H2O)2(BBC)](NO3)(DEF)6 (DUT-40), [Zn3(H2O)3(BBC)2] (DUT-41), [(C2H5)2NH2][Zn2(BBC)(TDC)](DEF)6(H2O)7 (DUT-42), [Zn10(BBC)5(BPDC)2(H2O)10](NO3)(DEF)28(H2O)8 (DUT-43), and [Co2(BBC)(NO3)(DEF)2(H2O)](DEF)6(H2O) (DUT-44), where BBC – 4,4′,4′′-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate, TDC – 2,5-thiophenedicarboxylate, BPDC – 4,4′-biphenyldicarboxylate, DEF – N,N-diethylformamide, were obtained under solvothermal conditions and structurally characterized. It has been shown that compounds DUT-40, DUT-41 and DUT-44 exhibit 2D layered structures with large hexagonal channels. Utilization of additional angular dicarboxylic TDC linker led to the formation of the DUT-42 compound with the structure consisting of three interpenetrated 3D networks. Using the linear co-linker dicarboxylic BPDC, DUT-43 was obtained which forms a complicated 3D architecture arising from the polycatenation of triple-layered 2D building units and 2D single layer units. The pore accessibility of the synthesized compounds in the liquid phase was proved by the adsorption of dye molecules.
- Andere Ausgabe
- DOI: 10.1039/c2dt12072k
- Volltext des Artikels, der zuerst in der Zeitschrift "Dalton transactions" des Royal Society of Chemistry-Verlages erschienen ist.
Link: http://dx.doi.org/10.1039/c2dt12072k - Freie Schlagwörter (DE)
- Metall-organische Gerüste, MOF, asymmetrische Katalyse, Kristall, Porosität, Dichte, Ligand
- Freie Schlagwörter (EN)
- metal-organic frameworks, heterogeneous asymmetric catalysis, crystals, porosity, density, design, ligand, mofs
- Klassifikation (DDC)
- 540
- Klassifikation (RVK)
- VA 1120
- Verlag
- Royal Society of Chemistry, Cambridge
- URN Qucosa
- urn:nbn:de:bsz:14-qucosa-138965
- Veröffentlichungsdatum Qucosa
- 08.04.2014
- Dokumenttyp
- Artikel
- Sprache des Dokumentes
- Englisch
- Lizenz / Rechtehinweis