Base catalysed decomposition of anthracene endoperoxide

  • Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.

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Metadaten
Author details:M. Klaper, Pablo WessigORCiDGND, Torsten LinkerORCiDGND
URN:urn:nbn:de:kobv:517-opus4-89676
Publication series (Volume number):Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (219)
Publication type:Postprint
Language:English
Date of first publication:2015/11/20
Publication year:2015
Publishing institution:Universität Potsdam
Release date:2016/04/12
First page:1210
Last Page:1213
Source:Chem. Commun. (2015) Nr. 52, S. 1210-1213. DOI: 10.1039/C5CC08606J
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
Publishing method:Open Access
License (German):License LogoKeine öffentliche Lizenz: Unter Urheberrechtsschutz
External remark:Bibliographieeintrag der Originalveröffentlichung/Quelle
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