[µ2-O,O′,Oʺ,Oʺ′-Bis(1,2-dithiooxalato-S,S′)nickel(II)]bis[-O,O′-bis(1,2-dithiooxalato-S,S′)-nickel(II)pentaquaholmium(III)]hydrate, [Ho2Ni3(dto)6(H2O)10]

  • Planar bis(1,2-dithiooxalato)nickelate(II), [Ni(dto)]2− reacts in aqueous solutions with lanthanide ions (Ln3+) to form pentanuclear, hetero-bimetallic complexes of the general composition [{Ln(H2O)n}2{Ni(dto)2}3]·xH2O. (n = 4 or 5; x = 9–12). The complex [{Ho(H2O)5}2{Ni(dto)2}3]·10H2O, Ho2Ni3, was synthesized and characterized by single crystal X-ray structure analysis and powder diffraction. The Ho2Ni3 complex crystallizes as monoclinic crystals in the space group P21/c. The channels and cavities, appearing in the crystal packing of the complex molecules, are occupied by a varying amount of non-coordinated water molecules.

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Metadaten
Author details:Jana König, Alexandra Kelling, Uwe SchildeORCiDGND, Peter StrauchGND
URN:urn:nbn:de:kobv:517-opus4-400598
Publication series (Volume number):Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (360)
Publication type:Postprint
Language:English
Date of first publication:2017/09/22
Publication year:2017
Publishing institution:Universität Potsdam
Release date:2017/09/22
Tag:1,2-dithiooxalate; crystal structure; holmium(III); lanthanides; nickel(II)
Number of pages:5
Source:Molbank 2016 Nr. 2. - DOI: 10.3390/M895
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
Publishing method:Open Access
Grantor:Multidisciplinary Digital Publishing Institute (MDPI)
License (German):License LogoCC-BY - Namensnennung 4.0 International
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