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Synthesis and solid state structures of a Ga-substituted distibene and the first Sb-analogue bicyclo[1,1,0]butane.

RGa {R=HC[C(Me)N(2,6‐iPr2C6H3)]2} reacts with Sb(NMe2)3 with insertion into the SbN bond and elimination of RGa(NMe2)2 (2), yielding the Ga‐substituted distibene R(Me2N)GaSb=SbGa(NMe2)R (1). Thermolysis of 1 proceeded with elimination of RGa and 2 and subsequent formation of the bicyclo[1.1.0]butane analogue [R(Me2N)Ga]2Sb4 (3).

Dedicated to Prof. M. Scheer on the occasion of his 60th birthday.

 

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Einordnung

alternativ:
A Gallium‐Substituted Distibene and an Antimony‐Analogue Bicyclo[1.1.0]butane: Synthesis and Solid‐State Structures
Datum der Veröffentlichung:
25.11.2020
URN:
urn:nbn:de:hbz:464-20201125-132736-0
DOI:
10.1002/anie.201502827
Sprache:
Englisch
Ressourcentyp:
Text
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Tuscher, L., Ganesamoorthy, C., Bläser, D., Wölper, C., Schulz, S.: A Gallium‐Substituted Distibene and an Antimony‐Analogue Bicyclo[1.1.0]butane: Synthesis and Solid‐State Structures. Angew. Chem. Int. Ed. 2015, 54,10657-10661, which has been published in final form at:
https://doi.org/10.1002/anie.201502827

Version of Record online: 06 August 2015

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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