Synthesis and Characterization of β-Diketiminate Zinc Complexes

The monomeric β‐diketiminate zinc complex (Mes)NacNacZnMe 1 (MesNacNac = {[2,6‐(2,4,6‐Me3‐C6H2)N(Me)C)]2CH}) was obtained in almost quantitative yield from the reaction of ZnMe2 with (Mes)NacNacH. Reaction of 1 with either Me3NHCl or a solution of HCl in Et2O yielded (Mes)NacNacZnCl 2, whereas (Mes)NacNacZnI 3 was obtained from the reaction of 1 with I2. 1–3 were characterized by elemental analyses, mass and multinuclear (1H, 13C{1H}) NMR spectroscopy, 3·THF also by single crystal X‐ray analysis.

Dedicated to Prof. Dr. Edgar Niecke on the occasion of his 70. birthday.

Vorschau

Einordnung

Datum der Veröffentlichung:
30.10.2020
URN:
urn:nbn:de:hbz:464-20201030-100248-9
DOI:
10.1002/zaac.200800374
Sprache:
Englisch
Ressourcentyp:
Text
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Z. Anorg. Allg . Chem. 2009, 635,216-220, which has been published in final form at:

https://doi.org/10.1002/zaac.200800374

Version of Record online: 11 February 2009

 

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

Zitieren

Zitierform:
Zitierform konnte nicht geladen werden.

Rechte

Nutzung und Vervielfältigung:
Alle Rechte vorbehalten