Hauptgruppenelement-Übergangsmetall-Mehrfachbindungen, IV. Katalytische Assistenz von [Cp(C0)\(_3\)Mo]\(_2\) bei der Aggregation von Metallo-arsanen über Arsen-Metall-Doppelbindungskomplexe

Main Group Element Transition Metal Multiple Bonds, IV. Catalytic Assistance by [Cp(CO)\(_3\)Mo]\(_2\) in the Aggregation of Metalloarsines via Arsenic Metal Double Bond Complexes

Please always quote using this URN: urn:nbn:de:bvb:20-opus-31424
  • The metallo-arsanes CP(CO)\(_3\)M - AsMc\(_2\) (1 a, b) (M = Mo, W) are convcrted to the double arsenido-bridged dinuclear complexes [(η-AsMe\(_2\))Mo(CO)\(_2\)Cp]\(_2\) (3a, b) in the presence of [CP(CO)\(_3\)Mo]\(_2\). Due to the unusual mild conditions of aggregation the intermediate formation of the double bonded species Cp(CO)\(_2\)M = AsMe\(_2\) (2a, b) is postulated. The crystal structure of 3a is reported, which shows mutual trans arrangement of the cyclopentadienyl and CO ligands.

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Metadaten
Author: Elisabeth Groß, Christian Burschka, Wolfgang Malisch
URN:urn:nbn:de:bvb:20-opus-31424
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Language:German
Year of Completion:1986
Source:Chemische Berichte (1986) 119, 1, 378-382.
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
GND Keyword:Chemie
Release Date:2009/11/25
Licence (German):License LogoDeutsches Urheberrecht