A neutral beryllium(I) radical

Please always quote using this URN: urn:nbn:de:bvb:20-opus-256529
  • The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, UV/Vis spectroscopy and X-ray crystallography. DFT calculations show significant spin density at beryllium and confirm donor–acceptor bonding between an alkylberyllium radical fragment and a neutral CAAC ligand.

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Metadaten
Author: Corinna Czernetzki, Merle Arrowsmith, Felipe Fantuzzi, Annalena Gärtner, Tobias Tröster, Ivo Krummenacher, Fabian Schorr, Holger BraunschweigORCiD
URN:urn:nbn:de:bvb:20-opus-256529
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Language:English
Parent Title (English):Angewandte Chemie International Edition
Year of Completion:2021
Volume:60
Issue:38
Pagenumber:20776–20780
Source:Angewandte Chemie International Edition (2021) 60:38, 20776–20780. DOI: 10.1002/anie.202108405
DOI:https://doi.org/10.1002/anie.202108405
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:Beryllium; EDA-NOCV; X-ray crystallography; cyclic alkyl(amino)carbene; radical
inorganic chemistry
Release Date:2022/02/24
Licence (German):License LogoCC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International