Adducts of the parent boraphosphaketene H\(_2\)BPCO and their decarbonylative insertion chemistry
Please always quote using this URN: urn:nbn:de:bvb:20-opus-256470
- The first examples of Lewis base adducts of the parent boraphosphaketene (H\(_2\)B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.
| Author: | Stephan Hagspiel, Felipe Fantuzzi, Rian D. Dewhurst, Annalena Gärtner, Felix Lindl, Anna Lamprecht, Holger BraunschweigORCiD |
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| URN: | urn:nbn:de:bvb:20-opus-256470 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Angewandte Chemie International Edition |
| Year of Completion: | 2021 |
| Volume: | 60 |
| Issue: | 24 |
| Pagenumber: | 13666–13670 |
| Source: | Angewandte Chemie International Edition (2021) 60:24, 13666–13670. DOI: 10.1002/anie.202103521 |
| DOI: | https://doi.org/10.1002/anie.202103521 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie |
| Tag: | boron; decarbonylation; heterocycles; inorganic chemistry; ketenes; phosphorus |
| Release Date: | 2022/02/24 |
| Licence (German): |  CC BY-NC: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell 4.0 International |