Main‐Group Metal Complexes in Selective Bond Formations Through Radical Pathways

Please always quote using this URN: urn:nbn:de:bvb:20-opus-214758
  • Recent years have witnessed remarkable advances in radical reactions involving main‐group metal complexes. This includes the isolation and detailed characterization of main‐group metal radical compounds, but also the generation of highly reactive persistent or transient radical species. A rich arsenal of methods has been established that allows control over and exploitation of their unusual reactivity patterns. Thus, main‐group metal compounds have entered the field of selective bond formations in controlled radical reactions. TransformationsRecent years have witnessed remarkable advances in radical reactions involving main‐group metal complexes. This includes the isolation and detailed characterization of main‐group metal radical compounds, but also the generation of highly reactive persistent or transient radical species. A rich arsenal of methods has been established that allows control over and exploitation of their unusual reactivity patterns. Thus, main‐group metal compounds have entered the field of selective bond formations in controlled radical reactions. Transformations that used to be the domain of late transition‐metal compounds have been realized, and unusual selectivities, high activities, as well as remarkable functional‐group tolerances have been reported. Recent findings demonstrate the potential of main‐group metal compounds to become standard tools of synthetic chemistry, catalysis, and materials science, when operating through radical pathways.show moreshow less

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Metadaten
Author: Crispin Lichtenberg
URN:urn:nbn:de:bvb:20-opus-214758
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Language:English
Parent Title (English):Chemistry – A European Journal
Year of Completion:2020
Volume:26
Issue:44
First Page:9674
Last Page:9687
Source:Chemistry – A European Journal 2020, 26(44):9674-9687. DOI: 10.1002/chem.202000194
DOI:https://doi.org/10.1002/chem.202000194
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Tag:bond formation; catalysis; main-group metals; organic and inorganic synthesis; radicals
Release Date:2021/04/19
Licence (German):License LogoCC BY-NC-ND: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell, Keine Bearbeitungen 4.0 International