- AutorIn
- Pierre Seidel
- Monika Mazik
- Titel
- Syntheses of Acyclic and Macrocyclic Compounds Derived from 9,9‐Diethylfluorene (Part I)
- Zitierfähige Url:
- https://nbn-resolving.org/urn:nbn:de:bsz:105-qucosa2-749609
- Quellenangabe
- ChemistryOpen
Erscheinungsjahr: 2020
Jahrgang: 9
Heft: 11
Seiten: 1202-1213
ISSN: 2191-1363 - Erstveröffentlichung
- 2020
- Abstract (EN)
- A series of new 9,9‐diethylfluorenes consisting of three side‐arms each bearing a heterocyclic, bis(carboxymethyl)amino, bis(carbamoylmethyl)amino, bis(ethoxycarbonylmethyl)amino or an amino group were prepared on the basis of 2,4,7‐tris(bromomethyl)‐9,9‐diethylfluorene. Imidazolyl, benzimidazolyl, pyrazolyl, pyrrolyl, 1,3‐dioxoisoindolyl and pyridinium groups were taken into account as heterocyclic units, attached to the aromatic skeleton via −CH2−, −CH2NHCH2− or −CH2N=CH− linkers. In addition to the seventeen 2,4,7‐trisubstituted 9,9‐diethylfluorenes, two macrocyclic compounds were prepared on the basis of 2,7‐bis(aminomethyl)‐9,9‐diethylfluorene. The excellent yield of the macrocyclization reaction is worth a special mention. Both the acyclic and the macrocyclic fluorene‐based compounds have, among other things, the potential to act as artificial receptors for different substrates in analogy to the known receptors consisting of a benzene or biphenyl core.
- Andere Ausgabe
- Zum Artikel, der zuerst in der Zeitschrift 'ChemistryOpen' erschienen ist:
Syntheses of Acyclic and Macrocyclic Compounds Derived from 9,9-Diethylfluorene (Part I)
DOI: 10.1002/open.202000268 - Freie Schlagwörter (DE)
- Publikationsfonds
- Freie Schlagwörter (EN)
- publishing fund, artificial receptors, fluorenophane, heterocycles, imines, macrocyclization
- Klassifikation (DDC)
- 540
- Normschlagwörter (GND)
- Fluren
- Flurenderivate
- Organische Synthese
- Heterocyclische Verbindungen
- Makrocyclische Verbindungen
- Verlag
- Wiley-VCH GmbH, Weinheim
- Sonstige beteiligte Institution
- Technische Universität Bergakademie Freiberg, Freiberg
- Version / Begutachtungsstatus
- publizierte Version / Verlagsversion
- URN Qucosa
- urn:nbn:de:bsz:105-qucosa2-749609
- Veröffentlichungsdatum Qucosa
- 20.10.2021
- Dokumenttyp
- Artikel
- Sprache des Dokumentes
- Englisch
- Lizenz / Rechtehinweis
- CC BY-NC-ND 4.0