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Solidification of Pb–Al Alloys Under the Influence of Electric Current Pulses

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Continuous solidification experiments are carried out with Pb–Al alloys under the influence of the electric current pulses (ECPs). The results demonstrate that the ECPs mainly affect the microstructure formation through changing the energy barrier for the nucleation of the minority phase droplets (MPDs) and minority phase particles (MPPs) during cooling Pb–Al alloys in the liquid–liquid and liquid–solid phase transformation temperature ranges in advance of the solidification of the matrix liquid. For Pb–Al alloys with Al-rich droplets/particles as the minority phase, the ECPs lower the energy barriers for the nucleation of the MPDs/MPPs and cause a significant increase in the nucleation rate of the MPDs/MPPs and, thus, promote the formation of Pb–Al alloys with a well-dispersed or even nanoparticles dispersed microstructure. The ECPs parameters show an important influence on the microstructure formation of Pb–Al alloys. The refinement extent of the MPDs/MPPs increases with the increase in the peak current density. For a given peak current density, the refinement extent of the MPDs/MPPs increases with the increases in the pulse frequency and pulse width first, and then level off and become asymptotic.

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References

  1. H.T. Yang, Z.C. Guo, B.M. Chen, H.R. Liu, Y.C. Zhang, H. Huang, X.L. Li, R.C. Fu, R.D. Xu, Hydrometallurgy 147–148, 148–156 (2014)

    Article  Google Scholar 

  2. W. Zhang, G. Houllachi, Hydrometallurgy 104, 129–135 (2010)

    Article  Google Scholar 

  3. H.T. Yang, H.R. Liu, Z.C. Guo, B.M. Chen, Y.C. Zhang, H. Huang, X.L. Li, R.C. Fu, R.D. Xu, Hydrometallurgy 140, 144–150 (2013)

    Article  Google Scholar 

  4. W.R. Osório, L.C. Peixoto, A. Garcia, J. Power Sour. 238, 324–335 (2013)

    Article  Google Scholar 

  5. C. Cachet, P.R. Le, R. Wiart, J. Appl. Electrochem. 28, 193–199 (1998)

    Article  Google Scholar 

  6. E.K. Alamdari, D. Darvishi, M.S. Khoshkhoo, F.A. Javid, S.P.H. Marashi, Hydrometallurgy 119–120, 77–86 (2012)

    Article  Google Scholar 

  7. A.J. McAllister, Bull. Alloy Phase Diagr. 5–1, 70 (1984)

    Google Scholar 

  8. X.F. Zhang, W.J. Lu, R.S. Qin, Mater. Res. Innov. 18, 244–248 (2014)

    Google Scholar 

  9. S.X. He, J. Wang, B.D. Sun, Y.H. Zhou, Trans. Nonferrous Met. Soc. China 12–3, 414–418 (2002)

    Google Scholar 

  10. M. Gao, G.H. He, F. Yang, J.D. Guo, Z.X. Yuan, B.L. Zhou, Mater. Sci. Eng., A 337, 110–114 (2002)

    Article  Google Scholar 

  11. G. Xu, Z. Wang, J. Yin, Y. Ding, S. Kou, J. Wuhan Univ. Technol. Mater. Sci. Ed. 21–1, 80–83 (2006)

    Google Scholar 

  12. C.Y. Ban, Y. Han, Q.X. Ba, J.Z. Cui, Mater. Sci. Forum 546–549, 723–728 (2007)

    Article  Google Scholar 

  13. H.S. Din, Y. Zhang, S.Y. Jiang, R.R. Chen, Z.L. Zhao, J.J. Guo, D.M. Xu, H.Z. Fu, China Foundry 6, 24–31 (2008)

    Google Scholar 

  14. M. Nakada, Y. Shiohara, M.C. Fleming, ISIJ Int. 30, 27–33 (1990)

    Article  Google Scholar 

  15. J. Li, S. Li, H. Lin, Scr. Metall. Mater. 31, 1691–1694 (1994)

    Article  Google Scholar 

  16. J.P. Banak, A.F. Sprecher, H. Conrad, Scr. Metall. Mater. 32, 879–884 (1995)

    Article  Google Scholar 

  17. R.S. Qin, B.L. Zhou, Int. J. Non-Equilibr. Process. 11, 77–86 (1998)

    Google Scholar 

  18. X. Liao, Q. Zhai, J. Luo, W. Chen, Y. Gong, Acta Mater. 55, 3103–3109 (2007)

    Article  Google Scholar 

  19. Y. Zhang, C. Song, L. Zhu, H. Zheng, H. Zhong, Q. Han, Q. Zhai, Metall. Mater. Trans. B 42, 604–611 (2011)

    Article  Google Scholar 

  20. J. Qi, L. Yang, S.A. Tukur, Z.F. Zhao, D. Wu, S. Dai, J.Z. Wang, Int. J. Sci. Technol. Res. 3, 267–274 (2014)

    Google Scholar 

  21. J. Li, J. Ma, Y. Gao, Q. Zhai, Mater. Sci. Eng., A 490, 452–456 (2008)

    Article  Google Scholar 

  22. J. Li, J. Ma, C.J. Song, Z.J. Li, Y.L. Gao, Q.J. Zhai, J. Iron. Steel Res. Int. 16–6, 07–12 (2009)

    Article  Google Scholar 

  23. F. Li, L.L. Regel, W.R. Wilcox, J. Cr. Gr. 223, 251–264 (2001)

    Article  Google Scholar 

  24. X. Liao, Q. Zhai, C. Song, W. Chen, Y. Gong, Mater. Sci. Eng., A 466, 56–60 (2007)

    Article  Google Scholar 

  25. J. Zhu, T. Wang, F. Cao, H. Fu, Y. Fu, H. Xie, T. Xiao, J. Mater. Eng. Perform. 22–5, 1319–1323 (2013)

    Article  Google Scholar 

  26. H.X. Jiang, J.Z. Zhao, C.P. Wang, X.J. Liu, Mater. Lett. 132, 66–69 (2014)

    Article  Google Scholar 

  27. H.X. Jiang, J. He, J.Z. Zhao, Sci. Rep. 5(12680), 1–8 (2015)

    Google Scholar 

  28. H. X. Jiang, Ph.D. Dissertation, Institute of Metal Research, Chinese Academy of Sciences, 2014 (in Chinese)

  29. H. Li, J.Z. Zhao, Q. Zhang, J. He, Metall. Mater. Trans. A 39, 3308–3316 (2008)

    Article  Google Scholar 

  30. A. Stanculescu, Thermophysical Properties of Materials for Nuclear Engineering: A Tutorial and Collection of Data (International Atomic Energy Agency, Vienna, 2008)

    Google Scholar 

  31. I. Takaimchi, I.L.G. Roderick, The Physical Properties of Liquid Metals (Oxford University Press Inc., New York, 1988)

    Google Scholar 

  32. S.Z. Beer, Liquid Metals (Marcel Dekker Inc., New York, 1972)

    Google Scholar 

  33. S. Taniguchi, J.K. Brimacombe, ISIJ Int. 34, 722–731 (1994)

    Article  Google Scholar 

  34. H.X. Jiang, J.Z. Zhao, J. He, J. Mater. Sci. Technol. 30–10, 1027–1035 (2014)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51771210, 51501207, 51471173 and 51271185); the China’s Manned Space Station Project (Grant No. TGJZ800-2-RW024); and the Natural Science Foundation of Liaoning Province (Grant No. 201501043).

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Correspondence to Jiu-Zhou Zhao.

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Ahmed, T., Jiang, HX., Li, W. et al. Solidification of Pb–Al Alloys Under the Influence of Electric Current Pulses. Acta Metall. Sin. (Engl. Lett.) 31, 842–852 (2018). https://doi.org/10.1007/s40195-017-0685-1

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  • DOI: https://doi.org/10.1007/s40195-017-0685-1

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