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Energy characteristics of nitrooxazolidines and their radicals

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Abstract

The standard molar enthalpies of combustion for three methyl and dimethyl nitrooxazolidine derivatives in the liquid and crystalline states were determined using a high-precision static bomb combustion calorimeter. The resulting values were used to derive the standard molar enthalpies of formation of the azidomethyl-N-nitrooxazolidines. The standard molar enthalpies of vaporization for these compounds were measured using a Calvet microcalorimeter. The enthalpies of formation of some nitrooxazolidine-derived radicals and biradicals were calculated.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, Moscow, 119991, Russian Federation

    E. A. Miroshnichenko, T. S. Kon’kova, Yu. N. Matyushin & Ya. O. Inozemtsev

  2. M. V. Lomonosov Moscow State University, Bl. 3, 1 Leninskie Gory, Moscow, 119991, Russian Federation

    L. L. Pashchenko

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow, 119991, Russian Federation

    V. A. Tartakovskii

Authors
  1. E. A. Miroshnichenko
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  2. T. S. Kon’kova
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  3. L. L. Pashchenko
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  4. Yu. N. Matyushin
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  5. Ya. O. Inozemtsev
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  6. V. A. Tartakovskii
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Corresponding author

Correspondence to E. A. Miroshnichenko.

Additional information

Based on the materials of the International Congress on the Heterocyclic Chemistry “KOST-2015” (October 18–23, 2015, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1876–1878, July, 2016.

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Miroshnichenko, E.A., Kon’kova, T.S., Pashchenko, L.L. et al. Energy characteristics of nitrooxazolidines and their radicals. Russ Chem Bull 65, 1876–1878 (2016). https://doi.org/10.1007/s11172-016-1524-7

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  • DOI: https://doi.org/10.1007/s11172-016-1524-7

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