Skip to main content
SpringerLink
Log in

Synthesis, structure, and catalytic activity of new aluminum and titanium complexes based on aminobisphenolate ligands containing bulky substituents

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A reaction of aminobisphenols EtN{CH2[(4-Alk)(6-But)(2-HO)C6H2]}2, Alk = Me (1); But (2) containing alkyl substituents in the phenol groups with trimethylaluminum and tetra(tert-butoxy)titanium gave two new aluminum derivatives with the Me–Al bond: EtN{CH2[(2-Alk)-(4-But)C6H2(2-O–)]}2Al–Me, Alk = Me (3); But (4), and two new titanium derivatives with the ButO–Ti bond: EtN{CH2[(2-Alk)(4-But)C6H2(2-O–)]}2Ti(O–But)2, Alk = Me (5); But (6). The structures of new compounds were confirmed by NMR spectroscopy and elemental analysis. The structures of complexes 3 and 6 were studied by X-ray crystallography. Complexes 3 and 6 are monomeric in the solid phase: a coordination number of Al atom is 4, that of Ti atom is 5, in addition to the M–O bonds the M←N interactions are also present. Complexes 3–6 were studied as initiators of the ring-opening polymerization of ε-caprolactone. The resulting polymers are characterized by relatively high values of number average molecular weight, with the polydispersity being relatively low.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. Dechy-Cabaret, B. Martin-Vaca, D. Bourissou, Chem. Rev., 2004, 104, 6147.

    Article  CAS  Google Scholar 

  2. J. Wu, T.-L. Yu, C.-T. Chen, C.-C. Lin, Coord. Chem. Rev., 2006, 250, 602.

    Article  CAS  Google Scholar 

  3. K. V. Zaitsev, S. S. Karlov, A. A. Selina, Yu. F. Oprunenko, A. V. Churakov, B. Neumüller, J. A. K. Howard, G. S. Zaitseva, Eur. J. Inorg. Chem., 2006, 1987.

    Google Scholar 

  4. K. V. Zaitsev, M. V. Bermeshev, A. A. Samsonov, Yu. F. Oprunenko, A. V. Churakov, J. A. K. Howard, S. S. Karlov, G. S. Zaitseva, New J. Chem., 2008, 32, 1415.

    Article  CAS  Google Scholar 

  5. M. Huang, E. Kh. Lermontova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, J. A. K. Howard, S. S. Karlov, G. S. Zaitseva, J. Organomet. Chem., 2009, 694, 3828.

    Article  CAS  Google Scholar 

  6. Yu. A. Piskun, I. V. Vasilenko, S. V. Kostjuk, K. V. Zaitsev, G. S. Zaitseva, S. S. Karlov, J. Polym. Sci., Part A: Polym. Chem., 2010, 48, 1230.

    Article  CAS  Google Scholar 

  7. M. Huang, M. M. Kireenko, K. V. Zaitsev, Yu. F. Oprunenko, A. V. Churakov, J. A. K. Howard, M. V. Zabalov, E. Kh. Lermontova, J. Sundermeyer, T. Linder, S. S. Karlov, G. S. Zaitseva, J. Organomet. Chem., 2012, 706–707, 66.

    Article  Google Scholar 

  8. M. M. Kireenko, E. A. Kuchuk, K. V. Zaitsev, V. A. Tafeenko, Y. F. Oprunenko, A. V. Churakov, E. Kh. Lermontova, G. S. Zaitseva, S. S. Karlov, Dalton Trans., 2015, 44, 11963.

    Article  CAS  Google Scholar 

  9. C.-T. Chen, C.-A. Huang, B.-H. Huang, Macromolecules, 2004, 37, 7968.

    Article  CAS  Google Scholar 

  10. A. J. Chmura, M. G. Davidson, M. D. Jones, M. D. Lunn, M. F. Mahon, Dalton Trans., 2006, 887.

    Google Scholar 

  11. A. J. Chmura, M. G. Davidson, M. D. Jones, M. D. Lunn, M. F. Mahon, A. F. Johnson, P. Khunkamchoo, S. L. Roberts, S. S. F. Wong, Macromolecules, 2006, 39, 7250.

    Article  CAS  Google Scholar 

  12. C.-T. Chen, C.-A. Huang, B.-H. Huang, Dalton Trans., 2003, 3799.

    Google Scholar 

  13. O. Wichmann, R. Sillanpää, A. Lehtonen, Coord. Chem. Rev., 2012, 256, 371.

    Article  CAS  Google Scholar 

  14. L. M. Alcazar-Roman, B. J. O’Keefe, M. A. Hillmyer, W.B. Tolman, Dalton Trans., 2003, 3082.

    Google Scholar 

  15. L.-C. Liang, S.-T. Lin, C.-C. Chien, J. Chin. Chem. Soc., 2013, 60, 710.

    Article  CAS  Google Scholar 

  16. E. Y. Tshuva, I. Goldberg, M. Kol, Z. Goldschmidt, Inorg. Chem., 2001, 40, 4263.

    Article  CAS  Google Scholar 

  17. L.-C. Liang, S.-T. Lin, C.-C. Chien, Inorg. Chem., 2013, 52, 1780.

    Article  CAS  Google Scholar 

  18. K. Phomphrai, P. Chumsaeng, P. Sangtrirutnugul, P. Kongsaeree, M. Pohmakotr, Dalton Trans., 2010, 39, 1865.

    Article  CAS  Google Scholar 

  19. Z. Tang, V. C. Gibson, Eur. Polym. J., 2007, 43, 150.

    Article  CAS  Google Scholar 

  20. Y. Sarazin, R. H. Howard, D. L. Hughes, S. M. Humphrey, M. Bochmann, Dalton Trans., 2006, 340.

    Google Scholar 

  21. D. Peri, C. M. Manna, M. Shavit, E. Y. Tshuva, Eur. J. Inorg. Chem., 2011, 2011, 4896.

    Article  CAS  Google Scholar 

  22. S. Barroso, P. Ado, M. T. Duarte, A. Meetsma, J. C. Pessoa, M. W. Bouwkamp, A. M. Martins, Eur. J. Inorg. Chem., 2011, 4277.

    Google Scholar 

  23. E. Safaei, M. Rasouli, T. Weyhermüller, E. Bill, Inorg. Chim. Acta, 2011, 375, 158.

    Article  CAS  Google Scholar 

  24. A. R. Hutchison, A. Mitra, D. A. Atwood, Main Group Chem., 2005, 4, 187.

    Article  CAS  Google Scholar 

  25. J. S. Klitzke, T. Roisnel, E. Kirillov, O. L. Casagrande, J.-F. Carpentier, Organometallics, 2014, 33, 5693.

    Article  CAS  Google Scholar 

  26. G. M. Sheldrick, Acta Crystallogr., 2008, A64, 112.

    Article  Google Scholar 

  27. G. M. Sheldrick, SADABS, Program for scaling and correction of area detector data, University of Göttingen, Germany, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, Moscow, 119991, Russian Federation

    E. A. Kuchuk, K. V. Zaitsev, G. S. Zaitseva, D. A. Lemenovsky & S. S. Karlov

  2. Baku Branch, M. V. Lomonosov Moscow State University, 1 ul. Universitetskaya, AZ1144, Baku, pos. Khodzhasan, Azerbaijan

    F. A. Mamedova

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., Moscow, 119991, Russian Federation

    A. V. Churakov

Authors
  1. E. A. Kuchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. V. Zaitsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. A. Mamedova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Churakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. S. Zaitseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. A. Lemenovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. S. Karlov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. V. Zaitsev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1743–1749, July, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kuchuk, E.A., Zaitsev, K.V., Mamedova, F.A. et al. Synthesis, structure, and catalytic activity of new aluminum and titanium complexes based on aminobisphenolate ligands containing bulky substituents. Russ Chem Bull 65, 1743–1749 (2016). https://doi.org/10.1007/s11172-016-1505-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-016-1505-x

Keywords

Search

Navigation