Abstract
The paper focuses on the electrical and structural characterization of nanostructurated ZrxLa1−xOy (ZLx) thin films in Zr atomic fractions in the range of x = 5 to 50%. High-k ZLx thin films were prepared on a Si(100) substrate using the sol-gel method. The influence of the annealing temperature in the presence of uniform oxygen flow (8 cm3/sec) on the insulator thickness was examined. It is found that the oxide growth versus time has parabolic behavior. The structure and morphology of the ZLx thin films were evaluated by x-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and transmission electron microscopy (TEM) techniques. Furthermore, material properties are investigated by x-ray photoelectron spectroscopy (XPS) analysis. The current density-voltage (J-V) and capacitance-voltage (C-V) characteristics are determined for Al/ZLx/Si devices. It is found that dielectric properties are sensitive to annealing conditions.
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Quinsaat JEQ, Nüesch FA, Hofmann H, Opris DM (2013) RSC Adv 3:6971
Ramprasad R, Shi N (2005) Phys Rev B 72:052107
Graca MPF, Silva CC, Costa LC, Valente MA (2010) Int J Nanoelectron Mater 3:99
Choi JH, Mao Y, Chang JP (2011) Mater Sci Eng R 72:97
Fang Q, Zhang JY, Wang ZM, Wu JX, O’Sullivan BJ, Hurley PK, Leedham TL, Davies H, Audier MA, Jimenez C, Senateur JP, Boyd IW (2003) Thin Solid Films 427:391
Chang JP, Lin YS (2001) Appl Phys Lett 79:3666
Matheswarana P, Sathyamoorthy R, Saravanakumar R, Velumani S (2010) Mater Sci Eng, B 174:269
Chang JP, Lin YS (2001) J Appl Phys 90:2964
Wu X, Migas DB, Li X, Bosman M, Raghavan N, Borisenk VE, Pey KL (2010) Appl Phys Lett 96:172901
Kidd T, O’Shea A, Boyle K, Wallace J, Strauss L (2011) Nanoscale Res Lett 6:294
Balamurugan A, Kannan S, Rajeswari S (2003) Mate Lett 57:4202
Kuei PY, Chou JD, Huang CT, Ko HH, Su SC (2011) J of Crystal Growth 314:81
Jeonga SH, Baea IS, Shina YS, Leea SB, Kwakb HT, Booa JH (2005) Thin Solid Films 475:354
Shimizu H, Asayama K, Kawai N, Nishide T (2004) Jpn J Appl Phys 43:6992
Li MF, Zhu CX, Shen CY, Xiong FF, Yuan P, Yeo YC, Chin A, Kwong DL, Wang SH, Du AY, Samudra G (2006) ECS Transactions 1:717
Yu XF, Zhu CX, Li MF, Chin A, Du AY, Wang WD, Kwong DL (2004) Appl Phys Lett 85:2893
Zhang MH, Rhee SJ, Kang CY, Choi CH, Akbar MS, Krishnan SA, Lee T, Ok IJ, Zhu F, Kim HS, Lee JC (2005) Appl Phys Lett 87:232901
Yamamoto Y, Kita K, Kyuno K, Toriumi A (2006) Appl Phys Lett 89:032903
Zhao C, Witters T, Brijs B, Bender H, Richard O, Caymax M, Heeg T, Schubert J, Afanas’ev V, Stesmans A, Schlom DG (2005) Appl Phys Lett 86:132903
Rauwel E, Doubourdieu C, Holländer B, Rochat N, Ducroquet F, Rossell MD, Van Tendeloo G, Pellissier B (2006) Appl Phys Lett 89:012902
Sathyamurthy S, Paranthaman M, Zhai HY, Christen HM, Martin PM, Goyal A (2002) J Mater Res 17:2181
Knoth K, Huhne R, Oswald S, Schultz L, Holzapfel B (2007) Acta Materialia 55:517
Bobzin K, Lugscheider E, Bagcivan N (2006) High Temp Mater Processes 10:103
Seo JW, Fompeyrine J, Guiller A, Norga G, Marchiori C, Siegwart H, Locquet JP (2003) Appl Phys Lett 83:5211
Gaskell M, Jones AC, Chalker PR, Werner M, Aspinall HC, Taylor S, Taechakumput P, Heys PN (2007) Chem Vap Deposition 13:684
Jauncey GEM, Pennell F (1933) Phys Rev B 43:505
Dimitrijev S, Barry Harrison H, Sweatman D (1996) IEEE TRANSA ON ELEC DEVI 43:267
SUPREM-3 TMA (1993) Technology Modeling Associates 1:2
Wang MT, Deng SY, Wang TH, Cheng BYY, Lee JYM (2005) J of The Electrochemi Soci 152:G542
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Gholipur, R., Bahari, A. & Ebrahimzadeh, M. Deposition of Nanostructurated Zr x La 1 − x O y Thin Films on P-type Si(100) Substrate by the Sol-Gel Route. Silicon 9, 173–181 (2017). https://doi.org/10.1007/s12633-015-9365-9
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DOI: https://doi.org/10.1007/s12633-015-9365-9