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Standard molar enthalpy of formation of [(C12H8N2)2Bi(O2NO)3] and its biological activity on Schizosaccharomyces pombe

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Abstract

The title complex [(C12H8N2)2Bi(O2NO)3] was synthesized by reaction of 1,10-phenanthroline (phen) and Bi(NO3)3·5H2O. The structure of the complex was characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. An advanced solution-reaction isoperibol microcalorimeter was applied to determine the standard molar enthalpies of formation at 298.15 K of the complex and Bi(NO3)3·5H2O, giving –(798.92 ± 5.99) and –(1986.87 ± 0.20) kJ mol−1, respectively. The biological effect of the complex was evaluated by microcalorimetry on the growth of Schizosaccharomyces pombe (S. pombe). According to thermogenic curves, the corresponding thermokinetics and thermodynamic parameters were derived. The complex had good bioactivity on the growth metabolism of S. pombe, with the value of IC50 being 2.8 × 10−5 mol L−1.

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Acknowledgements

The authors thank the National Natural Science Foundation of China (No. 21273190), The Project of Scientific Research of Hunan Provincial Education Department (15A175, 15A176, 14A134, 15C1272 and 16C1492), Science and Technology Plan Projects of Hunan Province (2014FJ3011, 2011TP4016-1 and 2012TP4021-5), and Science and Technology Plan Project of Chenzhou city (CKJ2016020) for financial support.

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  1. Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou, 423000, Hunan Province, People’s Republic of China

    Chuan-Hua Li, Yong Jiang, Jian-Hong Jiang, Xu Li, Sheng-Xiong Xiao, Li-Ming Tao, Fei-Hong Yao, Hui Zhang, Xian-Ming Xia, Long-Hua Yao, Hua Zhou, Ying-Hui Xiang, Yuan Tian & Qiang-Guo Li

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  1. Chuan-Hua Li
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Li, CH., Jiang, Y., Jiang, JH. et al. Standard molar enthalpy of formation of [(C12H8N2)2Bi(O2NO)3] and its biological activity on Schizosaccharomyces pombe . J Therm Anal Calorim 128, 1743–1751 (2017). https://doi.org/10.1007/s10973-017-6104-z

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