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Quantitative determination of hydroxyl groups on alumina by IR spectroscopy

Quantitative Bestimmung von Hydroxylgruppen an Aluminiumoxid durch IR-Spektroskopie

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  • Spectroscopic Methods
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Summary

Two methods were applied to study OH coverage of alumina with FTIR-spectroscopy:

  1. 1.

    Adsorption of well defined amounts of water (rehydration method);

  2. 2.

    Conversion of OH groups on alumina samples into the completely associated form by D2O adsorption.

OH coverage determination with these methods was applied to a major number of samples prepared in different ways (preheating without or with partial rehydration). On the basis of these results it was possible to derive a general relation allowing to determine the OH coverage of γ-alumina from the integration of the OH valence band in three partial wavenumber intervals.

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Authors and Affiliations

  1. Institut für Physikalische Chemie und Elektrochemie, Universität Düsseldorf, Universitätsstrasse 1, D-4000, Düsseldorf, Federal Republic of Germany

    E. Baumgarten, R. Wagner & C. Lentes-Wagner

Authors
  1. E. Baumgarten
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  2. R. Wagner
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  3. C. Lentes-Wagner
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Baumgarten, E., Wagner, R. & Lentes-Wagner, C. Quantitative determination of hydroxyl groups on alumina by IR spectroscopy. Z. Anal. Chem. 334, 246–251 (1989). https://doi.org/10.1007/BF00497251

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  • DOI: https://doi.org/10.1007/BF00497251

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