Abstract
The compressibility of γ-K2CO3 within the pressure range of 0.001-23.3 kbar and room temperature was determined by in situ synchrotron powder diffraction measurements in diamond anvil cell. The modification of the diffraction pattern was fixed at P > 23.3 kbar. This modification can be explained by a reconstructive phase transition. The amorphization of the high pressure phase was fixed on decompression.
References
A. Grzechnik, P. Bouvier, and L. Farina, J. Solid State Chem., 173, 13–19 (2003).
Z. Cancarevic, J. C. Schon, and M. Jansen, Z. Anorg. Allg. Chem., 632, 1437–1448 (2006).
Z. P. Cancarevic, J. C. Schon, and M. Jansen, Chem. Eur. J., 13, 7330–7348 (2007).
B. M. Gatehouse and D. J. Lloyd, J. Chem. Soc., Dalton Trans., 70–72 (1973).
N. Koura, S. Kohara, K. Takeuchi, S. Takahashi, L. A. Curtiss, M. Grimsditch, and M. L. Saboungi, J. Mol. Struct., 382, 163–169 (1996).
K. D. Litasov, A. Shatskiy, E. Ohtani, and G. M. Yaxley, Geology, 41, 79–82 (2013).
G. P. Brey, V. K. Bulatov, and A. V. Girnis, Chem. Geol., 281, 333–342 (2011).
G. E. Harlow, Am. Mineral., 82, 259–269 (1997).
A. F. Shatskii, Y. M. Borzdov, A. G. Sokol, and Y. N. Pal'yanov, Geol. Geofiz., 43, 940–950 (2002).
O. Navon, Nature, 353, 746–748 (1991).
Y. N. Pal'yanov, A. G. Sokol, Y. M. Borzdov, A. F. Khokhryakov, and N. V. Sobolev, Nature, 400, 417/418 (1999).
S. V. Rashchenko, A. Y. Likhacheva, and T. B. Bekker, High Pressure Res., 33, 702 (2013).
A. I. Ancharov, A. Y. Manakov, N. A. Mezentsev, B. P. Tolochko, M. A. Sheromov, and V. M. Tsukanov, Nucl. Instrum. Methods Phys. Res. A, 470, 80–83 (2001).
A. P. Hammersley, S. O. Svensson, M. Hanfland, A. N. Fitch, and D. Hausermann, High Pressure Res., 14, 235–248 (1996).
A. C. Larson and R. B. Von Dreele, Report LAUR, Los Alamos National Lab, New Mexico (2000), pp. 86–223.
G. P. Vassilev, Cryst. Res. Technol., 31, 647–657 (1996).
Y. Idemoto, J. W. Richardson, N. Koura, S. Kohara, and C. K. Loong, J. Phys. Chem. Solids, 59, 363–376 (1998).
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Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 7, pp. 1566-1569, September-October, 2016.
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Gavryushkin, P.N., Rashenko, S.V., Shatskiy, A.F. et al. Compressibility and phase transitions of potassium carbonate at pressures below 30 kbar. J Struct Chem 57, 1485–1488 (2016). https://doi.org/10.1134/S0022476616070258
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DOI: https://doi.org/10.1134/S0022476616070258