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Composites based on polyurethane–urea and ground rubber from car tyres: relation between structure and properties

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Abstract

The basis of this work is an investigation of multicomponent systems containing a reactive polyurethane–urea matrix, recycled rubber filler, and porosity. Rubber crumb with varying particle sizes obtained from used car tyres was used as the filler. As a matrix, water-curable isocyanate pre-polymer was used. Porosity was caused by the inability of the matrix to fully fill space between rubber particles, combined with foaming from matrix curing. We report on dependences of PUU/rubber system mechanical properties on the composition and structural parameters. Mechanical property values were obtained via tensile loading of prepared rectangular slabs. We found that mechanical behaviour exhibits strong correlation with a structural parameter called interspace filling, which expresses how much the matrix fills space between filler particles. Interspace filling is dependent on the degree of porosity and the volume fraction of the PUU matrix in a hypothetical nonporous material. Therefore, this work offers a simple characterization of complex materials, of which the studied porous composite is an example. Our results could contribute to the development of applications for large volumes of recycled rubber in materials used in rapid repair of roads and pavements.

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Abbreviations

E :

Elastic modulus (tensile) (MPa)

m :

Mass (g)

n :

Porosity (%)

n p :

Interspace filling (%)

T g :

Glass transition temperature (°C)

v :

Volume fraction (dimensionless)

v rubber :

Volume fraction of rubber in composite (dimensionless)

v i :

Volume fraction of the ith component of the theoretical nonporous composite (dimensionless)

v n :

Polyurethane–urea volume fraction in theoretical nonporous composite (dimensionless)

v p :

Polyurethane–urea volume fraction in porous composite (dimensionless)

ρ :

Density of composite (g cm−3, kg m−3)

ρ t :

Density of theoretical nonporous composite (g cm−3)

ρ i :

Density of the ith component of the composite (g cm−3)

σ :

Ultimate tensile strength (MPa, kPa)

References

  • Baatz G (1997) Canadian Patent No. 2,179,145. Canadian Intellectual Patent Office

  • Bower DK, Hicks S, Terry M, Peeler C, Galecki R, Tutumluer E (2011) International Patent No. 2,011,084,274. World Intellectual Property Organization

  • Bower DK, Hicks S, Terry M, Peeler CT (2015) Canadian Patent No. 2,784,986. Canadian Intellectual Patent Office

  • Cachaço AG, Afonso AD, Pinto M (2013) New applications for foam composites of polyurethane and recycled rubber. J Appl Polym Sci 129:2873–2881. doi:10.1002/app.38962

    Article  Google Scholar 

  • Cialone AM, Waznys P, Grubb M (2011) International Patent No. 3,011,153,399. World Intellectual Property Organization

  • Cong P, Xun P, Xing M, Chen S (2013) Investigation of asphalt binder containing various crumb rubbers and asphalts. Constr Build Mater 40:632–641. doi:10.1016/j.conbuildmat.2012.11.063

    Article  Google Scholar 

  • Danch A, Sułkowski WW, Moczyński M, Radoń A, Stelzer F, Jurga S (2004) Structural relaxation and morphology of rubber–urethane composites. J Appl Polym Sci 94:1186–1193. doi:10.1002/app.21027

    Article  CAS  Google Scholar 

  • Danch A, Ilisch S, Sułkowski WW, Moczyński M, Radoń A, Radusch H-J (2005) DMTA study of the urethane network in rubber waste–urethane composites. J Therm Anal Calorim 79(3):623–630

    Article  CAS  Google Scholar 

  • Garcia PS, de Sousa FDB, de Lima JA, Cruz SA, Scuracchio (2015) Devulcanization of ground tire rubber: physical and chemical changes after different microwave exposure times. Express Polym Lett 9:1015–1026. doi:10.3144/expresspolymlett.2015.91

    Article  CAS  Google Scholar 

  • Hicks S, Bower DK, Handlos WG, Kaul J, Arnott BT (2011) International Patent No. 2,010,149,737. World Intellectual Property Organization

  • Hughes AH, Pennington S (2004) Bonding of rubber particles. European Patent No. 1,400,561. European Patent Office

  • Johnston J, Zielinski S (2014) International Patent No. 2,014,031,568. World Intellectual Property Organization

  • Karger-Kocsis J, Felhös D, Xu D (2010) Mechanical and tribological properties of rubber blends composed of HNBR and in situ produced polyurethane. Wear 268:464–472. doi:10.1016/j.wear.2009.08.037

    Article  CAS  Google Scholar 

  • Karger-Kocsis J, Meszaros L, Barany T (2013) Ground tyre rubber (GTR) in thermoplastics, thermosets, and rubbers. J Mater Sci 48:1–38. doi:10.1007/s10853-012-6564-2

    Article  CAS  Google Scholar 

  • Kim JK (1997) Experimental and theoretical studies on crumb rubber/polyurethane blend system. Korea Polym J 5(4):241–247

    CAS  Google Scholar 

  • Maderuelo-Sanz R, Barrigon Morrilas JM, Martin-Castizo M, Escobar VG, Gozalo GR (2013) Acoustical performance of porous absorber made from recycled rubber and polyurethane resin. Latin Am J Solids Struct 10(3):585–600

    Article  Google Scholar 

  • Piszczyk Ł, Hejna A, Danowska M, Strankowski M, Formela K (2015a) Polyurethane/ground tire rubber composite foams based on polyglycerol: processing, mechanical and thermal properties. J Reinf Plast Compos 34:708–717. doi:10.1177/0731684415579089

    Article  CAS  Google Scholar 

  • Piszczyk Ł, Hejna A, Danowska M, Strankowski M, Formela K (2015b) Effect of ground tire rubber on structural, mechanical and thermal properties of flexible polyurethane foams. Iran Polym J 24:75–84. doi:10.1007/s13726-014-0301-4

    Article  CAS  Google Scholar 

  • Piszczyk Ł, Hejna A, Formela K, Danowska M, Strankowski M (2015c) Rigid polyurethane foams modified with ground tire rubber—mechanical, morphological and thermal studies. Cell Polym 34(2):45–62

    CAS  Google Scholar 

  • Potter GD, Shimizu F (1995) International Patent No. 1,995,025,076. World Intellectual Property Organization

  • Rodriguez-Alloza AM, Gallego J, Perez I (2013) Study of the effect of four warm mix asphalt additives on bitumen modified with 15% crumb rubber. Constr Build Mater 43:300–308. doi:10.1016/j.conbuildmat.2012.11.063

    Article  Google Scholar 

  • Sułkowski WW, Danch A, Moczyński M, Radoń A, Sulkowska A, Borek J (2004) Thermogravimetric study of rubber waste–polyurethane composites. J Therm Anal Calorim 78:905–921. doi:10.1007/s10973-005-0457-0

    Article  Google Scholar 

  • Sułkowski WW, Bartecka G, Sulkowska A, Maślanka S, Borek J, Moczyński M (2012) Thermogravimetric analysis of composites obtained from polyurethane and rubber waste. Mol Cryst Liq Cryst 556:39–51. doi:10.1080/15421406.2012.635907

    Article  Google Scholar 

  • Zhang X, Lu C, Liang M (2009) Properties of natural rubber vulcanizates containing mechanochemically devulcanized ground tire rubber. J Polym Res 16:411–419. doi:10.1007/s10965-008-9243-x

    Article  CAS  Google Scholar 

  • Zhang X, Lu Z, Tian D, Li H, Lu C (2012) Mechanochemical devulcanization of ground tire rubber and its application in acoustic absorbent polyurethane foamed composites. J Appl Polym Sci 127:4006–4014. doi:10.1002/app.37721

    Article  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Brno University of Technology, Purkyňova 464/118, 612 00, Brno, Czech Republic

    Miroslav Černý & Josef Jančář

  2. CEITEC, Brno University of Technology, Technická 3058/10, 616 00, Brno, Czech Republic

    Josef Jančář

Authors
  1. Miroslav Černý
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  2. Josef Jančář
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Correspondence to Miroslav Černý.

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This work was financially supported by the Project FCH-S-16-3864.

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Černý, M., Jančář, J. Composites based on polyurethane–urea and ground rubber from car tyres: relation between structure and properties. Chem. Pap. 71, 1119–1127 (2017). https://doi.org/10.1007/s11696-016-0060-0

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  • DOI: https://doi.org/10.1007/s11696-016-0060-0

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