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Metal phenyl compounds as cotatalysts in the homogeneous metathesis of alkenes

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Abstract

The application of several metal phenyl compounds as active cocatalysts in the homogeneous metathesis of alkenes with WCl or MoCl is described. Promising results have been obtained by using Sn(C6H5)4, Sn(C6H5)3Cl, Pb(C6H5)4 and Pb(C6H5)3Cl.

Abstract

Описывается применение некоторых металло-Фенильных соединений как активных кокатализаторов в гомогенном метатезисе алкенов, катализированном WCl6 или MoCl5. qHорошие результаты были получены при использовании Sn(C6H5)4, Sn(C6H5)3Cl, Pb(C6H5)4 и Pb(C6H5)3Cl.

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References

  1. N. Calderon, H. Y. Chen, K. W. Scott: Tetrahedron Lett., 3327 (1967)

  2. E. A. Zuech: Chem. Commun., 1182 (1968)

  3. E. A. Zuech, W. B. Hughes, D. H. Kubicek, E. T. Kittleman: J. Amer. Chem. Soc., 92, 528 (1970)

    Article  CAS  Google Scholar 

  4. W. B. Hughes: J. Amer. Chem. Soc., 92, 532 (1970)

    Article  CAS  Google Scholar 

  5. J. L. Wang, H. R. Menapace: J. Org. Chem., 33, 3794 (1968)

    Article  CAS  Google Scholar 

  6. J. L. wang, H. R. Menapace, M. Brown: J. Catal., 26, 455 (1972)

    Article  CAS  Google Scholar 

  7. T. Tagaki, T. Hamaguchi, K. Fukuzumi, M. Aoyama: Chem. Commun., No. 13. (1972).

  8. P. A. Raven, E. J. Wharton: Chem. and Ind., 292 (1972)

  9. C. P. C. Bradshaw: Brit. Patent 1, 208, 068 (1971) J. L. Herison, Y. Chauvin: Makromol. Chem., 141, 161 (1971) J. A. Moulijn, C. Boelhouwer: Chem. Commun., 1170 (1971) G. Pampus, G. Lehnert, D. Maertens: Polymer Preprints (Div. of Polymer Chemistry) 13, 880 (1972)

  10. P. B. van Dam, M. C. Mittelmeijer, C. Boelhouwer: Chem Commun., 1221 (1972)

  11. N. Calderon, E. A. Ofstead, J. P. Ward, W. A. Judy, K. W. Scott: J. Amer. Chem. 90, 4133 (1968)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute for Chemical Technology, University of Amsterdam, Amsterdam, The Netherlands

    P. B. van Dam & C. Boelhouwer

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  1. P. B. van Dam
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  2. C. Boelhouwer
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van Dam, P.B., Boelhouwer, C. Metal phenyl compounds as cotatalysts in the homogeneous metathesis of alkenes. React Kinet Catal Lett 1, 165–168 (1974). https://doi.org/10.1007/BF02067535

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