Abstract
According to microanalytical determinations the brutto formula of catechol-germanic acid should be written with two molecules of water. The thermal decomposition of this compound takes place with liberation of catechol; liberation of water can be excluded. Pyridine-germanium catecholate, however, decomposes by liberating pyridine, but no catechol is set free. The results clearly show that these two compounds have different molecular structures:
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Dem Vorstand des Institutes für Physikalische Chemie der Universität Wien, Herrn Prof. Dr. H. Nowotny, danken wir für wertvolle Diskussionen.
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Konopik, N., Liptay, G., Blaha, H. et al. Differentialthermoanalytische, derivativ thermogravimetrische und thermogravimetrische Untersuchungen von Brenzcatechin-Germaniumsäure und Pyridin-Germanium-Brenzcatechinat. Journal of Thermal Analysis 6, 231–235 (1974). https://doi.org/10.1007/BF01911504
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DOI: https://doi.org/10.1007/BF01911504