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Photocatalytic oxidation of substituted toluenes with irradiated TiO2 semiconductor. Effect of zeolite

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Abstract

Photocatalytic oxidation of substituted toluenes was investigated on irradiated TiO2 and TiO2 combined with HY15 and HY20 zeolites. In all cases the oxidation occurred in the first step exclusively on either one substituent or the other, but never on both simultaneously. In the presence of a zeolite, photooxidation conversion was higher than that obtained without zeolite.

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References

  1. O. Beaune, A. Finiels, P. Geneste, P. Graffin, J.L. Olive and A. Saaedan, J. Chem. Soc. Chem. Commun. (1992) 1649.

  2. O. Beaune, A. Finiels, P. Geneste, P. Graffin, A. Guida, J.L. Olive and A. Saaedan, in:Heterogeneous Catalysis and Fine Chemicals III, Studies in Surface Science and Catalysis, Vol. 78, eds. M. Guisnet, J. Barbier, J. Barrault, C. Bouchoule, D. Duprez, G. Pérot and C. Montassier (Elsevier, Amsterdam, 1993) p. 401.

    Google Scholar 

  3. A. Saaedan, Doctoral Thesis, Ecole Nationale Supérieure de Chimie de Montpellier, Université de Montpellier, France (1992).

    Google Scholar 

  4. M. Fujihira, Y. Satoh and T. Osa, Chem. Lett. (1981) 1053.

  5. M. Fujihira, Y. Satoh and T. Osa, J. Electroanal. Chem. 126 (1981) 277.

    Google Scholar 

  6. J.A. Navio, M. Garcia Gomez, A. Pradera Adrian and J. Fuentas Mota, in:Heterogeneous Catalysis and Fine Chemicals II, Studies in Surface Science and Catalysis, Vol. 59, eds. M. Guisnet, J. Barrault, C. Bouchoule, D. Duprez, G. Pérot, R. Maurel and C. Montassier (Elsevier, Amsterdam, 1991) p. 445.

    Google Scholar 

  7. M.N. Mozzanega, J.M. Herrmann and P. Pichat, Tetrahedron Lett. (1977) 2965.

  8. P. Pichat, J. Disdier, J.M. Herrmann and P. Vaudano, Nouv. J. Chim. 10 (1986) 548.

    Google Scholar 

  9. N.S. Isaacs,Reactive Intermediates in Organic Chemistry (Wiley, New York, 1974).

    Google Scholar 

  10. E. Baciocchi, G.C. Rosato, C. Rol and G.V. Sebastiani, Tetrahedron Lett. 33 (1992) 5437.

    Google Scholar 

  11. A. Onopchenko, J.G.D. Schulz and R. Seekircher, J. Org. Chem. 37 (1972) 1414.

    Google Scholar 

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Bouquet-Somrani, C., Finiels, A., Geneste, P. et al. Photocatalytic oxidation of substituted toluenes with irradiated TiO2 semiconductor. Effect of zeolite. Catal Lett 33, 395–400 (1995). https://doi.org/10.1007/BF00814241

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  • DOI: https://doi.org/10.1007/BF00814241

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