Skip to main content
Log in

Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - 1,2-Dichloroethane

  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

This risk assessment on 1,2-dichloroethane (EDC) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 21 studies for fish, 17 studies for invertebrates and 7 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 1100 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.5 µg EDC/l and a worst case PEC of 6.4 µg EDC/l. The calculated PEC/PNEC ratios give a safety margin of 170 to 2200 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  • Agence de Bassin Seine Normandie (1995)-Personal communication

  • Ahmad, N., Benoit, D., Brooke, L., Call, D., Carlson, A., De Foe, D., Huot, J., Mariarity, A., Richter, J., Shubat, P., Veith, G., Wallbridge, C. (1984): Aquatic toxicity tests to characterise the hazard of volatile organic chemicals in water: A toxicity data summary — parts III and II; NTIS/PB 84-141506; US Department of Commerce, Springfield, VA, 3–7, 9–13, 16–25,27, 29–32, 34–42, 45, 48, 50, 53, 54

    Google Scholar 

  • Arbeitsgemeinschaft zur Reinhaltung der Weser-Gütebericht (1993)-Published 1994

  • Arge Elbe (1982); Chlorierte Kohlenwasserstoffe, Daten der Elbe; Bericht ueber die Ergebnisse des Schwerpunktmessprogramms-Chlorierte Kohlenwasserstoffe im Elbabschnitt von Schnackenburg bis zur Nordsee, (1980–82): 22–28

  • AWWR (1983–86); Bericht des Ruhrverbandes Ruhrwasserguete im Wasserwirtschaftjahr (1983–86); Arbeitsgemeinschaft der Wasserwerke and der Ruhr

  • Barrows, M.E., Petrocelli, S.R., Macek, K.J., Carroll, J.J. (1978): Bioconcentration and elimination of selected water pollutants by bluegill sunfish (Lepomis macrochirus) in dynamics, exposure and hazard assessment of toxic chemicals-R. Hague Ed.; Ann Arbor, Michigan, Ann Arbor Science 379–392

    Google Scholar 

  • Bartlett, E.A. (1979): NTIS/OTS 0517174 # 86-870002085

  • Bauer (1978); Halogenkohlenwasserstoffe im Trrink-und Oberflächenwasser. Messergebnisse 1976/77 in der Bundesrepublik Deutscvhland (Trinkwasser aus 100 Städten, Oberflächenwasser aus Ruhr, Lippe, Main, Rhein); WaBoLu-Berichte, 3: 64–74

    Google Scholar 

  • Benoit, D.A., Puglisi, F.A., Olson, D.L. (1982): A fathead minnow Pimephales promelas early life stage toxicity test method evaluation and exposure to four organic chemicals; Environ. Pollut. Ser. A Ecol. Biol. 28, 189–197

    Google Scholar 

  • Bianchi, A.P., Varney, M.S., Phillips, J. (1991); Analysis of volatile organic compounds in estuarine sediments using dynamic headspace and gas chromatography-mass spectrometry; J. Chromatography 542: 413–450

    Google Scholar 

  • Black, J.A., Birge, W.J., McDonnell, W.E., Westerman, A.G., Ramey, B.A. und Bruser, D.M. (1982); The aquatic toxicity of organic compounds to embryo-larval stages of fish and amphibians, 1–61; NTIS/PB 82-224601, US Department of Commerce, Springfield, VA

    Google Scholar 

  • Bringmann, G. (1975): Bestimmung der biologischen Schadwirkung wassergefahrdender Stoffe aus der Hemmung der Zellvermehrung der Blaualge microcystis; Gesundheits-Ingenieur 96, 238–241

    Google Scholar 

  • Bringmann, G.; Kuehn, R. (1976): Vergleichende Befunde der Schadwirkung wassergefahrdender Stoffe gegen Bakterien (Pseudomonas putida) und Blaualgen (Microcystis aeruginosa); Gas-Wasserfach, Wasser-Abwasser (GWF) 117, 410–413

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1977): Results of the damaging effect of water pollutants on Daphnia magna; Z. Wasser Abwasser Forsch. 10, 161–166

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1978a): Testing of substances for their toxicity threshold: model organisms Microcystis (diplocystis) aeruginosa and Scenedesmus quadricauda; Mitt. Internat. Verein. Limnol. 21, 275–284

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1978b): Limiting values for the noxious effects of water pollutant material to blue algae (Microcystis aeruginosa) and green algae (Scenedesmus quadricauda) in cell propagation inhibition tests; Vom Wasser 50, 45–60

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1979): Vergleich der toxischen Grenzkonzentrationen wassergefahrdender Stoffe gegen Bakterien, Algen und Protozoen im Zellvermehrungshemmtest; Haustechn. Bauphys. Umwelttech. 100,249–252

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1980): Comparison of the toxicity thresholds of water pollutants to bacteria, algae and protozoa in the cell multiplication inhibition test; Water Research 14, 231–241

    Google Scholar 

  • Bringmann, G., Kuehn, R. (1982): Ergbnisse der Schadwirkung Wassergefährdender Stoffe gegen Daphnia magna in einem weiterentwickelten standardisierten Testverfahren; Z. Wasser Abwasser Forsch. 151, 1–6

    Google Scholar 

  • Brooke, L.T. et al. (eds) (1985). Acute toxicities of organic chemicals to Fathead minnows (Pimephales promelas), vol I, II and III. Center for Lake Superior Environmental Studies, University of Wisconsin-Superior.

    Google Scholar 

  • BUA (1995)-Stoffbericht 163 1,2 Dichloroethane-Stand Dezember (1994), Wissenschaftliche Verlagsgesellschaft, S. Hirzel

  • Buccafusco, R.J., Ells, S.J., LeBlanc, G.A. (1981): Acute toxicity of priority pollutants to bluegill (Lepomis macrochirus); Bull. Environ. Contam. Toxicol. 26, 446–452

    Google Scholar 

  • Call, D.J., Brooke, R.J., Ells, S.J., LeBlanc, G.A. (1983): Toxicity and metabolism studies with EPA priority pollutants and related chemicals in freshwater organisms; NTIS/PB 83, 623–655

  • Council Directive 93/72/EEC (Official Journal L258, 16/10.93) on classification, packaging and labelling of dangerous substances

  • Commission Regulation 94/1488/EEC (Official Journal L161, 29/06/94) laying down the principles for the assessment of risks to, man and the environment of existing substances in accordance with Council Regulation (EEC) No 793/93

  • Council Directive 90/415/EEC (Official Journal L219, 14/08/90) amending Annex II to Directive 86/280/EEC on limit values and quality objectives for discharges of certain dangerous substances included in list I of the Annex to Directive 76474/EEC

  • Dawes, V.J., Waldock, M.J. (1994): Estuarine contamination — VOC, halogenated solvents, BTEX — measurement of volatile organic compounds at UK national monitoring plan stations; Marine Pollut. Bulletin, 28(5): 291–298

    Google Scholar 

  • Dawson, G.W., Jennings, A.L., Drozdowski, D., Rider, E. (1977): The acute toxicity of 47 industrial chemicals to fresh and saltwater fishes; J. Hazard. Mater. 1, 303–318

    Google Scholar 

  • De Rooij, C. (1994)-The impact of waste water from the chemical industry on the quality of the marine environment — Changes with time-Paper presented at “10 years Belgica” Symposium Ostend, (17–19 Oct. 1994)

  • Dilling W.L., Tefertiller, N.B., Kallos, G.J. (1975): Evaporation rates and reactivities of methylene chloride, chloroform, 1,1,1-trichloroethane, trichloroethylene, tetrachloroethylene, and other chlorinated compounds in dilute aqueous solutions; Env. Sci. Technol. 833–838

  • DKRR — Deutsche Kommission zur Reinhaltung des Rheins: Zahlentafeln der physikalisch-chemischen Untersuchungen (1993)-Bericht Oct 1995-ISSN O173-1653

  • DoE Environmental Hazard Assessment 1,2-dichloroethane, TSD/8 (1992)

  • ECVM — European Council of Vinyl Manufacturers (August 1994)-On the environmental impact of the manufacture of PVC-A description of Best Available Technique

  • Foster, G.D., Tullis, R.E. (1984): A quantitative structure-activity relationship between partition coefficients and the acute toxicity of naphthalene derivatives in artemia salina nauplii; Aquat. Toxicol. 5, 245–254

    Google Scholar 

  • Foster, G.D., Tullis, R.E. (1985): Quantitative structure-toxicity relationships with osmotically stressed artemia salina nauplii; Environm. Pollution (Series A):38, 273–281

    Google Scholar 

  • Freitag, D., Ballhorn, L., Behechti, A., Fisher, K., Thumm, W. (1994): Structural configuration and toxicity of chlorinated alkanes; Chemosphere 282: 253–259

    Google Scholar 

  • Gewässergütebericht Elbe (1993) mit Zahlentafeln Ed. Internationale Kommission zum Schutz der Elbe, Magdeburg (Nov 1994), Author: Dr. H. Reincke

  • Gosset, R.W., Brown, D.A. and Young, D.R. (1983); Predicting the bioaccumulation of organic compounds in marine organisms using octanol/water partition coefficients; Marine Poll. Bull. 387–392

  • Heitmuller, P.T., Hollister, T.A., Parrish, P.R. (1981): Acute toxicity of 54 industrial chemicals to sheepshead minnows (cyprinodon variegatus); Bull. Environ. Contam. Toxicol. 27, 596–604

    Google Scholar 

  • Howard, C.J., Evenson, K.M. (1976). Rate constants for the reactions of OH with ethane and some halogen substituted ethanes at 296 K.; J. Chem. Phys. 64, 4303–4306

    Google Scholar 

  • IPCC (1997); Greenhouse Gas Inventory, Reference Manual; Intergovernmental Panel on Climate Change Guidelines for National Greenhouse Gas Inventories, Vol. 3, OECD (Organisation for Economic Cooperation and Development), Paris, France, 1997

    Google Scholar 

  • IUCLID (1996) International Uniform Chemical Information Database — Data Sheet — 1,2-dichloroethane; European Chemical Bureau, Ispra, Italy-CD-Rom

    Google Scholar 

  • Janus, J, Hesse J.M.: Aandachtstoffen in het Nederlandse Milieubeleid-Overzicht (1994)-., MGJ Rikken Ets (Nov 1994)-Rapport No601014006 van Rijksinstituut voor Volksgezondheid en Milieuhygiene-Bilthoven

  • Johnson, W.W., Finley, M.T. (1980): Handbook of Acute Toxicity of Chemicals to Fish and Aquatic Invertebrates, United States Department of the Interior Fish and Wildlife Service/Resource Publication 137, Washington, D.C., 1–3, 83, 86

    Google Scholar 

  • Juhnke, I., Luedemann, D. (1978): Ergebnisse der Untersuchung von 200 chemischen verbindungen auf akute Fishtoxizität mit dem Goldorfentest; Z. Wasser Abwasser Forsch. 11(5), 161–164

    Google Scholar 

  • Kerster, H.W., Schaeffer, D.J. (1983): Brine shrimp (artemia salina nauplii) as a teratogen test system; Ecotoxicol. Environ. Safety 7, 342–349

    Google Scholar 

  • Knie, J., Haelke, A., Juhnke, I., Schiller, W. (1983): Ergebnisse der Untersuchungen von chemischen Stoffen mit Vier Biotests; Dtsch. Gewaesserkundl. Mitt. 27(3), 77–79

    Google Scholar 

  • Koenemann, H. (1981): Quantitative structure-activity relationships in fish toxicity studies — part 1: relationship for 50 industrial pollutants; Toxicology 19, 209–221

    Google Scholar 

  • Kuehn, R., Pattard, M., Pernak, K.D. (1989): Results of the harmful effects of selected water pollutants (anilines, phenols, aliphatic compounds) to daphnia magna; Water Res. 23, 495–499

    Google Scholar 

  • LWA (1989–92); Gewässergütebericht (1988–91); Landesamt für Wasser und Abwasser Nordrhein Westfalen

  • LWA (1988); Grundwasserbericht (1987); Landesamt für Wasser und Abfall Nordrhein Westfalen

  • Mackay, D., Patterson, S. (1990) Fugacity models; in: Karcher, W. Devillers, J. (Eds); Practical applications of quantitative structure-activity relations in environmental chemistry and toxicology. 433–460

  • MAFF report-Ministry of Agriculture, Fisheries and Food Aquatic environment Monitoring Report Number 44 1993 Data-Published in 1995

  • Mayer, F.L. Fr. Ellersieck, M.R. (1986): Manual of acute toxicity: interpretation and data base for 410 chemicals and 66 species of freshwater animals; United States Department of the Interior Fish and Wildlife Service/Publication 160, Washington, D.C.,-117, 30–32, 216

    Google Scholar 

  • Ministerie van Verkeer en Waterstaat (1994); Meetwaarden in Schelde, Doel, (1993)

  • NRA report-National Rivers Authority-River Tees Environmental Quality Standard Monitoring 1995 Data-Published in 1996

  • Ostfeldt, P., Gustavson, K., Jansson, B., Jonsson, P., Miettinen, V., Ringstad, O., Wesen, C. (1994); Halogenated Organic Compounds in the Marine Environment 1989–1990; TemNord 591; Nordic Council of Ministers, Copenhagen 1994

    Google Scholar 

  • Pearson, C.R., McConnell, G. (1975): Chlorinated C1 and C2 hydrocarbons in the marine environment; Proc. R. Soc. London, Ser. B. 189(1096), 305–332

    Google Scholar 

  • Pedersen, F., Tyle, H. Niemelä, J.R., Guttmann, B., Lander, L., Wedebrand, A. (1994) Environmental Hazard Classification — Data Collection and interpretation guide; TemaNord 1994:589

  • Price, K.S., Waggy, G.T., Conway, R.A. (1974): Brine shrimp bioassay and seawater BOD of petrochemicals; J. Water Pollut. Control. Fed. 46, 63–77

    Google Scholar 

  • Rapport sur l'Etat du Rhin-Analyses physico-chimiques et biologiques jusqu'en 1991-CIPR (Sept 1993)

  • Reid, B.J. Morgan J.D., Whelen, M.A. (1982): A preliminary examination of the effects of ethylene dichloride on the hatchability of coho salmon eggs (oncorhynchus kisutch); Can. Techn. Rep. Fish. Aquat. Sci. 1163, 145–153

    Google Scholar 

  • Richter, J.E., Peterson, S.F., Kleiner, C.F. (1983): Acute and chronic toxicity of some chlorinated benzenes, chlorinated ethanes, and tetrachloroethylene to daphnia magna; Arch. Environ. Contam. Toxicol. 12: 679–684

    Google Scholar 

  • Rinehart, W.E. (1971): NTIS/OTS 0516114 # 86-870001211

  • RIVM (1993); Monitoring of radioactivity and xenobiotic substances in the environment; The Netherlands, 1991

  • RIWA (1990–91); Samenwerkende Rijn-en Maas-waterleidingbedrijven; Samenstelling van het Rijnwater in 1990–91; Delft, 1993

  • RIWA (1995); Association des Services d'Eau du Rhin et de la Meuse; Tome B: Meuse (1993); Amsterdam, 1995

    Google Scholar 

  • Rosenberg R., Grahn, O., Johansson, L. (1975): Toxic effects of aliphatic chlorinated by-products from vinyl chloride production on marine animals; Water Res., 9(7), 607–12

    Google Scholar 

  • Sanchez-Fortun, S., Sanz, F., Santa-Maria, A., Ros, J.M., De Vicente, M.L., Encinas, M.T., Vinagre, E., Barahona, M.V. (1997); Acute sensitivity of three age classes of Artemia salina larvae to seven chlorinated solvents; Bull. Environ. Contam. Toxicol., 59, pp. 445–451

    Google Scholar 

  • Scherb K. (1978); Untersuchungen zur Ausdampfung einiger niedermolekularer Chlorkohlen wasserstoffe aus einem Fliessgerinne; Munch. Beitr. Abwasser, Fish. Flussbiol. 30, 235–248

    Google Scholar 

  • Syracuse Res. Corp. (1978b): NTIX/OTS 0511060 # 40-7848049

  • Syracuse Res. Corp. (1978a): NTIS/OTS 0516114

  • Takahashi, N., Nakai, T., Satoh, Y., Katoh, Y. (1994); Variation of biodegradability of nitrogenous organic compounds by ozonation; Wat. Res. 28(7) 1563–1570

    Google Scholar 

  • TGD (1996)-Technical Guidance Documents in support of the Commission Directive 93/67/EEC on Risk Assessment for new notified substances and the Commission Regulation (EC) 94/1488/EEC on risk assessment for existing substances (Parts I, II, III and IV) EC Catalogue numbers CR-48-96-001-EN-C, CR-48-96-002-EN-C, CR-48-96-003-EN-C, CR-48-96-004-EN-C

  • UK Department of the Environment, 1994: Environmental hazard assessment: carbon tetrachloride; Building Research Establishment, Watford, UK

    Google Scholar 

  • Umweltbundesamt (1994); Daten zur Umwelt, (1992/93)-Erich Schmidt Verlag GmbH-Berlin

    Google Scholar 

  • UN-ECE (United Nations Economic Commission for Europe) (1994); Protocol concerning the Control of Emissions of Volatile Organic Compounds and their Transboundary Fluxes, Annex IV: Classification of volatile organic compounds (VOCs) based on their photochemical ozone creation potential (POCP), UN, Geneva, Switzerland, 92 pp.

  • UNEP (1998); United Nations Environment Programme, Nairobi, Kenya-The 1987 Montreal Protocol was lastly revised by the Ninth Meeting of the Parties in Montreal, 15–17 September 1997

  • UN-FCCC (1997); Kyoto Protocol to the United Nations Framework Convention on Climate Change, UN document No FCCC/CP/1997/L.7/Add.1 of 10 December 1997, UNFCCC, Bonn, Germany

    Google Scholar 

  • US EPA (1978): In-depth studies on health and environmental impacts of selected water pollutants cited in US EPA (1980): NTIS/PB 81-117400

  • US EPA; Safe Drinking Water Act: National primary and secondary drinking water regulations-Maximum contaminant levels for organic and inorganic chemicals; FEREAC.40, 59570 (1975); Amendment CFRUS.40, 141 (1991)

  • Van de Meent, D., Den Hollander, H.A., Pool, W.G., Vredenbregt, M.J., Van Oers, H.A.M., De Greef, E., Luyten, J.A. (1986); Organic micropollutants in Dutch coastal waters; Water Sci. Technol., 18: 73–81

    Google Scholar 

  • van Ginkel, C.G. (1988); Biodegradability of Monochloroacetic acid (Technical report); Akzo Research Laboratories Arnhem

  • Veith, G.D., Call, D.J., Brooke, L.T. (1983): Structure-toxicity relationships for the fathead minnow, Pimephales promelas: narcotic industrial chemicals; Can. J. Fish. Aquat. Sci. 40, 743–748

    Google Scholar 

  • von Tümpling, W. (1972); Ein manometrisches Verfahren zur Bestimmung der autotrophen Bioaktivität; Fortschritte der Wasserchemie 14, 205–213

    Google Scholar 

  • Walbridge, C.T., Phipps, G.L., Holcombe, G.W. (1983): Acute toxicity of ten chlorinated aliphatic hydrocarbons to the fathead minnow; Arch. Environ. Contam. Toxicol. 12, 661–666

    Google Scholar 

  • Wallington, T.J., Bilde, M., Mogelberg, T.E., Sehested, J., Nielsen, O.J. (1996); J. Phys. Chem. 100, 5751–5760

    Google Scholar 

  • WHO Guidelines for drinking water quality (1993); 2nd Ed., ISBN 92-4-154460-0

  • Wilson J.T., McNabb, J.F., Balkwill, D.L., Ghiorse, W.V. (1983): Enumeration and characterization of bacteria indigenous to a shallow water-table aquifer; Ground Water 21, 134–142

    Google Scholar 

  • WMO (World Meteorological Organization): Global ozone research and monitoring project; Report No 37; Scientific assessment of Ozone Depletion 1994; WMO Geneva, Chapter 13

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

De Rooij, C., Boutonnet, JC., Garny, V. et al. Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - 1,2-Dichloroethane. Environ Monit Assess 53, 425–445 (1998). https://doi.org/10.1023/A:1006062532209

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1006062532209

Navigation