Skip to main content
Log in

Solution processed CuI/n-Si junction device annealed with and without iodine steam for ultraviolet photodetector applications

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

We report the fabrication and characterization of a facile and low-cost solution processed CuI/Si junction device for ultraviolet photodetector applications. The properties of CuI films are analyzed by Hall-effect measurement, X-ray diffraction pattern, ultraviolet–visible absorption spectrum, and field emission scanning electron microscope. The amount of iodine vacancies of CuI could be adjusted through subsequence anneals with/without iodine steam. Moderate process would improve the CuI crystallization and reduce iodine vacancies, and so thus raise the photocurrent and photo responsivity of CuI/Si junction. The made junction device performs a maximum Iphoto/Idark ratio of 3 × 104 to an ultraviolet light of 365 nm wavelength.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. W.D. Li, S.Y. Chou, Solar-blind deep-UV band-pass filter (250–350 nm) consisting of a metal nano-grid fabricated by nanoimprint lithography. Opt. Express. 18, 931–937 (2010)

    Article  CAS  Google Scholar 

  2. M. Razeghi, A. Rogalski, Semiconductor ultraviolet detectors. J. Appl. Phys. 79, 7433–7473 (1996)

    Article  CAS  Google Scholar 

  3. E. Monroy, F. Omnes, F. Calle, Wide-bandgap semiconductor ultraviolet photodetectors. Semicond. Sci. Technol. 18, R33 (2003)

    Article  CAS  Google Scholar 

  4. C. Soci, A. Zhang, B. Xiang, S.A. Dayeh, D.P.R. Aplin, J. Park, X.Y. Bao, Y.H. Lo, D. Wang, ZnO nanowire UV photodetectors with high internal gain. Nano Lett. 7, 1003–1009 (2007)

    Article  CAS  Google Scholar 

  5. N. Prakash, M. Singh, G. Kumar, A. Barvat, K. Anand, P. Pal, S.P. Singh, S.P. Khanna, Ultrasensitive self-powered large area planar GaN UV-photodetector using reduced graphene oxide electrodes. Appl. Phys. Lett. 109, 242102 (2016)

    Article  Google Scholar 

  6. S.X. Yang, J. Gong, Y. Deng, A sandwich-structured ultraviolet photodetector driven only by opposite heterojunctions. J. Mater. Chem. 22, 13899–13902 (2012)

    Article  CAS  Google Scholar 

  7. F. Alema, B. Hertog, O. Ledyaev, D. Volovik, R. Miller, A. Osinsky, S. Bakhshi, W.V. Schoenfeld, High responsivity solar blind photodetector based on high Mg content MgZnO film grown via pulsed metal organic chemical vapor deposition. Sens. Actuators A Phys. 249, 263–268 (2016)

    Article  CAS  Google Scholar 

  8. V. Adinolfi, O. Ouellette, M.I. Saidaminov, G. Walters, A.L. Abdelhady, O.M. Bakr, E.H. Sargent, Fast and sensitive solution-processed visible-blind perovskite UV photodetectors. Adv. Mater. 33, 7264–7268 (2016)

    Article  Google Scholar 

  9. W. Gruzintsev, Zagorodnev, Effect of annealing on the luminescence of p-CuI crystals. Semiconductors 46, 149–154 (2011)

    Article  Google Scholar 

  10. P.M. Sirimanne, M. Rusop, T. Shirata, T. Soga, T. Jimbo, Characterization of transparent conducting CuI thin films prepared by pulse laser deposition technique. Chem. Phys. Lett. 366, 485–489 (2002)

    Article  CAS  Google Scholar 

  11. M. Xia, M. Gun, X. Liu, S. Sun, B. Liu, S. Huang, C. Ni, AAO-assisted synthesis of CuI nanowires by vacuum melting and gas pressure injection. Mater. Lett. 153, 14–17 (2015)

    Article  CAS  Google Scholar 

  12. M.N. Amalina, Y. Azilawati, N.A. Rasheid, M. Rusop, The properties of copper (I) iodide (CuI) thin films prepared by mister atomizer at different doping concentration. Proc. Eng. 56, 731–736 (2013)

    Article  CAS  Google Scholar 

  13. J.H. Lee, D.S. Leem, J.J. Kim, High performance top-emitting organic light-emitting diodes with copper iodide-doped hole injection layer. Org. Electron. 9, 805–808 (2008)

    Article  CAS  Google Scholar 

  14. P.M. Sirimanne, T. Soga, T. Jimbo, Identification of various luminescence centers in CuI films by cathodoluminescence technique. J. Lumin. 105, 105–109 (2003)

    Article  CAS  Google Scholar 

  15. Y. Liu, J. Zhan, J. Zeng, Y. Qian, K. Tang, W. Yu, Ethanolthermal synthesis to I3-CuI nanocrystals at low temperature. J. Mater. Sci. Lett. 20, 1865–1867 (2001)

    Article  CAS  Google Scholar 

  16. F.L. Schein, H.V. Wenckstern, M. Grundmann, Transparent p-CuI/n-ZnO heterojunction diodes. Appl. Phys. Lett. 102, 092109 (2013)

    Article  Google Scholar 

  17. J. Liu, Y. Zhang, C. Liu, M. Peng, A. Yu, J. Kou, W. Liu, J. Zhai, J. Liu, Piezo-phototronic effect enhanced UV photodetector based on CuI/ZnO double shell grown on flexible copper microwire. Nanoscale Res. Lett. 11, 281 (2016)

    Article  CAS  Google Scholar 

  18. Z. Zheng, A. Liu, S. Wang, B. Huang, K.W. Wong, X. Zhang, S.K. Hark, W.M. Lau, Growth of highly oriented (110) γ-CuI film with sharp exciton band. J. Mater. Chem. 18, 852–854 (2008)

    Article  CAS  Google Scholar 

  19. B.A. Nejand, V. Ahmadi, H.R. Shahverdi, Growth of plate like γ-CuI nanostructure on copper substrate by hydrothermal evaporation of solution. Mater. Lett. 132, 138–140 (2014)

    Article  CAS  Google Scholar 

  20. M.R. Johan, K.S. Wen, N. Hawari, N.A.K. Aznan, Synthesis and characterization of copper(I) iodide nanoparticles via chemical route. Int. J. Electrochem. Sci. 7, 4942–4950 (2012)

    CAS  Google Scholar 

  21. P.M. Sirimanne, M. Rusop, T. Shirata, T. Soga, T. Jimbo, Characterization of CuI thin films prepared by different techniques. Mater. Chem. Phys. 80, 461–465 (2003)

    Article  CAS  Google Scholar 

  22. J. Wang, J. Li, S.S. Li, Native p-type transparent conductive CuI via intrinsic defects. J. Appl. Phys. 110, 054907 (2011)

    Article  Google Scholar 

  23. D. Roy, G.F. Samu, M.K. Hossain, C. Janaky, K. Rajeshwar, On the measured optical bandgap values of inorganic oxide semiconductors for solar fuels generation. Catal. Today 300, 136–144 (2018)

    Article  CAS  Google Scholar 

  24. G.C. Lin, F.Z. Zhao, Y. Zhao, D.Y. Zhang, L.X. Yang, X. Xue, X.H. Wang, C. Qu, Q.S. Li, L.C. Zhang, Luminescence properties and mechanisms of CuI thin films fabricated by vapor iodization of copper films. Materials 9, 990 (2016)

    Article  Google Scholar 

  25. Y.Y. Lv, L.W. Ye, Z.J. Zhang, B.B. Zhang, Z.H. Xu, X.X. Zhuang, S.H. Yao, G.B. Su, Growth habit and optical properties of γ-CuI single crystals via a temperature difference method. RSC Adv. 5, 71514–71518 (2015)

    Article  CAS  Google Scholar 

  26. S. Dutta, S. Chattopadhyay, M. Sutradhar, A. Sarkar, M. Chakrabarti, D. Sanyal, D. Jana, Defects and the optical absorption in nanocrystalline ZnO. J. Phys. Condens. Matter. 19, 236218–236218 (2007)

    Article  Google Scholar 

  27. Y. Shan, G.W. Li, G. Tian, J.Z. Han, C.S. Wang, S.Q. Liu, H.L. Du, Y.C. Yang, Description of the phase transitions of cuprous iodide. J. Alloys Compd. 477, 403–406 (2009)

    Article  CAS  Google Scholar 

  28. V. Aubry, F. Meyer, Schottky diodes with high series resistance: limitations of forward I–V methods. J. Appl. Phys. 76, 7973 (1994)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Ministry of Science and Technology, Taiwan, through Grant No. 104-2221-E-018-020. The authors thank the Department of Physics, National Changhua University of Education for providing the equipment.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu Wu Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, Y.W., Chuang, C.Y. Solution processed CuI/n-Si junction device annealed with and without iodine steam for ultraviolet photodetector applications. J Mater Sci: Mater Electron 29, 18622–18627 (2018). https://doi.org/10.1007/s10854-018-9980-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-9980-5

Navigation