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The New Complexes of Selected Transition Metal Ions with a Ligand Formed by Condensation of Isatin with Amino Acid: Spectral, Thermal, and Magnetic Properties

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Abstract

The new complexes of 2-[(2-oxo-1,2-dihydroindol-3-ylidene)amino]butanoic acid, LH (where L = C12H11N2O3), with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) of general formulae MLCl·nH2O, for Co(II), Ni(II) and Cu(II), and ML2·H2O for Mn(II) and Zn(II), where n = 1, 2 depending on M(II) ions, are synthesized. The complexes crystallize in a monoclinic system, and upon heating in the air (293–1173 K) decompose in three steps forming eventually the corresponding oxides of the metals(II). In the course of this process the organic ligand decomposes releasing the molecules of H2O, CO2, NH3, CO, hydrocarbons, and additionally HCl for Co(II), Ni(II) and Cu(II) complexes. Magnetic moments of compounds are determined in the ranges of 76–303 and 2–300 K. All analyzed compounds, except that of Zn(II), demonstrate the paramagnetic properties with the ferro- and antiferromagnetic interactions between molecular centres.

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References

  1. Pandeya, S.N., Siram, D., Nath, G., and Declercq, E., Eur. J. Pharm. Sci., 1999, vol. 9, p. 25. doi S0928-0987 (99)00038-X

    Article  CAS  PubMed  Google Scholar 

  2. Thompson, K.H. and Orvig, C., J. Chem. Soc., Dalton Trans., 2006, no. 6, p. 761. doi 10.1039/b513476e

    Article  Google Scholar 

  3. Rodrigues-Arguelles, M.C., Ferrari, M.B., Bisceglie, F., Pelizzi, C., Pelosi, G., Pinelli, S., and Sassi, M., J. Inorg. Biochem., 2004, vol. 98, p. 313. doi 10.1016/j.jinorgbio.2003.10.006

    Article  CAS  Google Scholar 

  4. Cerchiaro, G., Aquilano, K., Filomeni, G., Rotilio, G., Ciriolo, M.R., and Ferreira, A.M.D.C., J. Inorg. Biochem., 2005, vol. 99, p. 1433. doi 10.1016/j.jinorgbio.2005.03.013

    Article  CAS  PubMed  Google Scholar 

  5. Rabia, M.K., Mohamad, M.D.A., Ismail, N.M., and Mahmoud, A.A., J. Iranian Chem. Soc., 2013, vol. 10, no. 12, p. 1. doi 10.1134/S1070363213120487

    Google Scholar 

  6. Sridhar, S.K., Pandeya, S.N., Stables, J.P., and Ramesh, A., Eur. J. Pharm. Sci., 2002, vol. 16, p. 129. doi S0928-0987(02)00077-5

    Article  CAS  PubMed  Google Scholar 

  7. Penthala, N.R., Yerramreddy, T.R., Madadi, N.R., and Crooks, P.A., Bioorg. Med. Chem. Lett., 2010, vol. 20, no. 15, p. 4468. doi 10.1016/j.bmcl.2010.06.042

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. Pandeya, S.N., Smitha, S., Jyoti, M., and Sridhar, S.K., Acta Pharm., 2008, vol. 66, p.43.

    Google Scholar 

  9. Imam, S.A. and Varma, R.S., Experientia, 1975, vol. 31, p. 1287.

    Article  CAS  PubMed  Google Scholar 

  10. Ade, S.B., Deshpande, M.N., and Deshmukh, J.H., Rasayan J. Chem., 2012, vol. 5, no. 1, p.10.

    CAS  Google Scholar 

  11. Singh, H.L. and Singh, J.B., Res. Chem. Intermed., 2013, vol. 39, p. 1997. doi 10.1007/s11164-012-0732-5

    Article  CAS  Google Scholar 

  12. Hassaan, A.M.A., Transit. Met. Chem., 1990, vol. 15, p.283.

    Article  CAS  Google Scholar 

  13. Figgis, B.N. and Nyholm, R.S., J. Chem. Soc., 1958, p. 4190. doi 10.1039/JR9580004190

    Google Scholar 

  14. Prabakarakrishnan, R., Manoranjitham, S., and Geetha, K., WJPR., 2014, vol. 3(9), p. 1286.

    CAS  Google Scholar 

  15. Silverstein, R.M., Bassler, G.S., and Morrill, T.C., Spectrometric Identification of Organic Compounds., New York: John Wiley and Sons, 1995, p.99.

    Google Scholar 

  16. Bridson, A.K., Inorganic Spectroscopic Methods, New York: Oxford University Press, 1988, p.75.

    Google Scholar 

  17. Maity, D., Chattopadhyay, S., Ghosh, A., Drew, M.G.B., and Mukhopadhyay, G., Inorg. Chim. Acta, 2011, vol. 365, p. 25. doi 10.1016/j.ica.2010.07.029

    Article  CAS  Google Scholar 

  18. Maruthyunjaya Swamy, B.H.M., Ijare, O.M., and Jadegoud, Y., J. Braz. Chem. Soc., 2005, vol. 16(4), p. 783. doi 10.1590/S0103-50532005000500016

    Article  Google Scholar 

  19. Rathore, K., Singh, R.R., and Singh, H.B., J. Chem., 2010, vol. 7(S1), p. S566. doi 10.1155/2010/521843

    CAS  Google Scholar 

  20. Kumar, B., Prasad, K.K., and Srivastawa, S.K., Orient. J. Chem., 2010, vol. 26(4), p. 1413.

    CAS  Google Scholar 

  21. Malik, S., Ghosh, S., and Jain, B., Arch. Apll. Sci. Res., 2010, vol. 2(2), p.304.

    CAS  Google Scholar 

  22. Dorokhtei, I.L., Seifullina, I.I., and Zubkov, S.V., Russ. J. Coord. Chem., 2003, vol. 29, no. 10, p.714.

    Article  CAS  Google Scholar 

  23. Bojarski, Z. and Lagiewka, E., Structural X-Ray Analysis, Warsaw: Polish Scientific Publisher, 1988, p.244.

    Google Scholar 

  24. Boultif, A. and Louer, D. J., Appl. Cryst., 2004, vol. 37, p. 724. doi 10.1107/S0021889804014876

    Article  CAS  Google Scholar 

  25. Nikolaev, A.V., Logvinienko, A.V., and Myachina, L.I., Thermal Analysis, New York: Academic Press, 1969, p.58.

    Google Scholar 

  26. Paulik, F., Special Trends in Thermal Analysis., Chichester: John Wiley and Sons, 1995, p.139.

    Google Scholar 

  27. Lyszczek, R. and Mazur, L., Polyhedron, 2012, vol. 41, p. 7. doi 10.1016/j.poly.2012.04.009

    Article  CAS  Google Scholar 

  28. Zielinski, W. and Rajca, A., Spectroscopic Methods and Their Application to Identification of Organic Compounds, Warsaw: WNT, 1995.

    Google Scholar 

  29. Dawid, C.W., J. Chem. Educ., 1996, vol. 73(1), p. 46. doi 10.1021/ed073p46

    Article  Google Scholar 

  30. D’Hendecourt, L.B., Allamandola, L.J., and Greenberg, J.M., Astron. Astrophys., 1985, vol. 152(1), p.130.

    Google Scholar 

  31. O’Connor, Ch.J., Progress in Inorganic Chemistry, New York: John Wiley and Sons, 1982, p.260.

    Google Scholar 

  32. Cotton, A.F., Wilkinson, G., Advanced Inorganic Chemistry, New York: John Wiley and Sons, 1988, p.955.

    Google Scholar 

  33. Drzewiecka-Antonik, A., Ferenc, W., Wolska, A., Klepka, M. T., Cristóvao, B., Sarzynski, J., Rejmak, P., and Osypiuk, D., Chem. Phys. Lett., 2017, vol. 667, p. 192. doi 10.1016/j.cplett.2016.11.053

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Department of General and Coordination Chemistry, Maria Curie-Skłodowska University, Lublin, 20031, Poland

    W. Ferenc, D. Osypiuk & H. Głuchowska

  2. Institute of Physics, Maria Curie-Skłodowska University, Lublin, 20031, Poland

    J. Sarzyński

Authors
  1. W. Ferenc
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  2. D. Osypiuk
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  3. J. Sarzyński
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  4. H. Głuchowska
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Correspondence to W. Ferenc.

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Ferenc, W., Osypiuk, D., Sarzyński, J. et al. The New Complexes of Selected Transition Metal Ions with a Ligand Formed by Condensation of Isatin with Amino Acid: Spectral, Thermal, and Magnetic Properties. Russ J Gen Chem 88, 1525–1532 (2018). https://doi.org/10.1134/S1070363218070277

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