@article{Burger1989ansam-23951,
  year={1989},
  doi={10.1016/0022-328X(89)80004-X},
  title={ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors},
  number={2},
  volume={378},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={153--161},
  author={Burger, Peter and Hund, Hans-Ulrich and Evertz, Kaspar and Brintzinger, Hans-Herbert}
}

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    <dcterms:abstract xml:lang="eng">The product of an Mg/CCl&lt;sub&gt;4&lt;/sub&gt;-induced reductive coupling of guaiazulene reacts with TiCl&lt;sub&gt;3&lt;/sub&gt;·3THF to yield, after oxidation with HCl/O&lt;sub&gt;2&lt;/sub&gt;, R,S-8,8′-biguaiazulenide titanium dichloride, which contains a CC bond between its two guaiazulenide ligand moieties. A similar reaction sequence starting from 3-phenyl-1,2-dihydropentalene gives unbridged R,S-bis(4-exo-phenyl-4H-5,6-dihydropentalenide)titanium dichloride.</dcterms:abstract>
    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
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    <dc:contributor>Hund, Hans-Ulrich</dc:contributor>
    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <dc:contributor>Evertz, Kaspar</dc:contributor>
    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 378 (1989), 2. - S. 153-161</dcterms:bibliographicCitation>
    <dcterms:title>ansa-metallocene derivatives : XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors</dcterms:title>
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